I think it's obvious. Which photo was created by flash and which using sun light? I artificially create a "rim" light with a flash, however occasionally (not all that often really) we can do the same thing with sun light. For the left photo we happen to be in the near perfect location to use the sun light.
We were at a hotel along the Camden waterfront with the Philadelphia skyline behind us. Plus, we had a beautiful day in February. We couldn't have had a nicer day.
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